Of course Damon doesn't want anything bad to happen to Stefan, but I'm sure that part of his concern here has to do with the fact that if the werewolf bite gets him and Stefan dies in the sacrifice, Elena is left alone to transform
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And in a pivotal moment in "The Last Day" he acts out of that emotion and does something that, though it is to save Elena (Nina Dobrev), he will soon come to regret.
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